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Atomistry » Phosphorus » Chemical Properties » Phosphorus Dichloride | ||
Atomistry » Phosphorus » Chemical Properties » Phosphorus Dichloride » |
Phosphorus Dichloride, (PCl2)n
By the action of a silent electric discharge upon a mixture of the gaseous trichloride and hydrogen a liquid was obtained which, after filtration to remove a yellow solid and distillation under reduced pressure, proved to have a composition corresponding to PCl2. It decomposed quickly on heating into PCl3 and a yellow solid, boiled with decomposition at about 180° C. and could be frozen to a solid which melted at -28° C.
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