Atomistry » Phosphorus » Chemical Properties » Triphosphonitrilic Chloride
Atomistry »
  Phosphorus »
    Chemical Properties »
      Triphosphonitrilic Chloride »

Triphosphonitrilic Chloride, P3N3Cl6

Triphosphonitrilic Chloride, P3N3Cl6, forms large rhombic crystals of density 1-98. Its properties are typical of those found in the series. It is easily soluble in the usual organic solvents, also in glacial acetic acid and sulphuric acid, undergoing reaction with the latter. It also reacts with many organic compounds containing hydroxyl groups—alcohols, phenols, etc. Aniline when added to the benzene solution gave a dianilide, NP(NH.C6H5)2. Ammonia when passed into a solution of P3N3Cl6 in carbon tetrachloride gave needles of a chloroamide, possibly P3N3Cl4(NH2)2, which was insoluble in organic solvents. Liquid ammonia gave a white solid hexamide, P3N3(NH2)6. Hydrolysis proceeds when an ether solution is shaken with water, with production first of P3N3Cl4(OH)2, then of trimetaphosphimic acid, [NH(POOH)]3 and HCl, and finally ammonium phosphate.

Last articles

Zn in 9JYW
Zn in 9IR4
Zn in 9IR3
Zn in 9GMX
Zn in 9GMW
Zn in 9JEJ
Zn in 9ERF
Zn in 9ERE
Zn in 9EGV
Zn in 9EGW
© Copyright 2008-2020 by atomistry.com
Home   |    Site Map   |    Copyright   |    Contact us   |    Privacy