Atomistry » Phosphorus » Chemical Properties » Triphosphonitrilic Chloride
Atomistry »
  Phosphorus »
    Chemical Properties »
      Triphosphonitrilic Chloride »

Triphosphonitrilic Chloride, P3N3Cl6

Triphosphonitrilic Chloride, P3N3Cl6, forms large rhombic crystals of density 1-98. Its properties are typical of those found in the series. It is easily soluble in the usual organic solvents, also in glacial acetic acid and sulphuric acid, undergoing reaction with the latter. It also reacts with many organic compounds containing hydroxyl groups—alcohols, phenols, etc. Aniline when added to the benzene solution gave a dianilide, NP(NH.C6H5)2. Ammonia when passed into a solution of P3N3Cl6 in carbon tetrachloride gave needles of a chloroamide, possibly P3N3Cl4(NH2)2, which was insoluble in organic solvents. Liquid ammonia gave a white solid hexamide, P3N3(NH2)6. Hydrolysis proceeds when an ether solution is shaken with water, with production first of P3N3Cl4(OH)2, then of trimetaphosphimic acid, [NH(POOH)]3 and HCl, and finally ammonium phosphate.

Last articles

Zn in 7VD8
Zn in 7V1R
Zn in 7V1Q
Zn in 7VPF
Zn in 7T85
Zn in 7T5F
Zn in 7NF9
Zn in 7M4M
Zn in 7M4O
Zn in 7M4N
© Copyright 2008-2020 by atomistry.com
Home   |    Site Map   |    Copyright   |    Contact us   |    Privacy