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Tetraphosphonitrilic Chloride, P4N4Cl8

Tetraphosphonitrilic Chloride, P4N4Cl8, forms colourless prisms, density 2.18. The molar weight was determined by vapour density and depression of the freezing-point of benzene. Solubility relations are similar to those of the tripolymer. An octoanilide, {NP(NHC6H52}4, has been prepared. Like the trinitrilic chloride it was scarcely affected by water alone, but an ether solution gave first an hydroxychloride and then tetrametaphosphimic acid, [NH(POOH)]4.2H2O.

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